MoO42− as a soluble inhibitor for Zn in neutral and alkaline solutions

Shkirskiy, Viacheslav; Keil, P.; Hintze-Bruening, Horst; Leroux, Fabrice; Stimpfling, Thomas; Dragoé, Diana; Ogle, K.; Volovitch, P.

doi:10.1016/j.corsci.2015.05.005

Cited by 34 publications

(24 citation statements)

References 48 publications

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“…Behavior of Coated Samples. The reduced Zn dissolution, detached area of polymer, and higher R ct values for HDG coated with Zn 2 Al/-MoO 4 2− LDH fillers can be associated with the release of MoO 4 2− from the hybrid coating system in the presence of 0.1 M NaHCO 3 confirming the earlier reported 41 inhibiting properties of soluble molybdates on HDG.…”

Section: Effect Of Carbonates On the Corrosionsupporting

confidence: 83%

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Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Shkirskiy

Keil

Hintze-Bruening

et al. 2015

ACS Appl. Mater. Interfaces

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Zn2Al/-layered double hydroxide (LDH) with intercalated MoO4(2-) was investigated as a potential source of soluble molybdate inhibitor in anticorrosion coatings for hot dip galvanized steel (HDG). The effect of solution pH, soluble chlorides, and carbonates on the release kinetics of the interleaved MoO4(2-) ions from the LDH powder immersed in solutions containing different anions was studied by X-ray diffraction, in situ attenuated total reflectance infrared (ATR-IR) spectroscopy, and inductively coupled plasma atomic emission spectroscopy (ICP-AES). The effect of the solution composition on the total release and the release kinetics was demonstrated. Less than 30% of the total amount of the intercalated MoO4(2-) was released after 24 h of the immersion in neutral 0.005-0.5 M NaCl and 0.1 M NaNO3 solutions whereas the complete release of MoO4(2-) was observed after 1 h in 0.1 M NaHCO3 or Na2SO4 and in alkaline solutions. The in situ ATR-IR experiments and quantification of the released soluble species by ICP-AES demonstrated the release by an anion exchange in neutral solutions and by the dissolution of Zn2Al/-LDH in alkaline solutions. The anion exchange kinetics with monovalent anions was described by the reaction order n = 0.35 ± 0.05 suggesting the diffusion control; for divalent anions, n = 0.70 ± 0.06 suggested the control by a surface reaction. Dissolution of Zn from coated HDG with and without Zn2Al/-MoO4(2-) fillers, leaching of MoO4(2-) from the coating, and the electrochemical impedance spectroscopy response of the coated systems were measured during the immersion in 0.5 M NaCl solutions with and without 0.1 M NaHCO3. Without carbonates, the release of soluble MoO4(2-) was delayed for 24 h with no inhibiting effect whereas with 0.1 M NaHCO3 the immediate release was accompanied by the immediate and strong inhibiting effect on Zn dissolution. The concept of controlling the inhibition performance of LDH hybrid coatings by means of the environment composition is discussed.

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Section: Effect Of Carbonates On the Corrosionsupporting

confidence: 83%

“…The choice of the inhibitor was motivated by the reported earlier high inhibiting efficiency of soluble MoO 4 2− comparable in some conditions with the efficiency of CrO 4 2− . 41 The first part of the work presents the effect of the solution composition…”

Section: Introductionmentioning

confidence: 99%

Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Shkirskiy

Keil

Hintze-Bruening

et al. 2015

ACS Appl. Mater. Interfaces

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“…MoO 4 2− conversion to brown colored Mo (III,IV) oxides, instead of Mo 0 on the Zn surface in neutral and acid conditions has been previously observed. [ 30 ] Such reactions corroded the Zn surface, as indicated by Figure 3C2,4, where the Mo‐rich region and Zn‐barren region are highly correlated. In addition, the electrochemically plated Zn has a mixed morphology of roughened rods, plates, and rods.…”

Section: Resultsmentioning

confidence: 95%

Achieving Stable Molybdenum Oxide Cathodes for Aqueous Zinc‐Ion Batteries in Water‐in‐Salt Electrolyte

Wang

Yan

Quilty

et al. 2021

Adv Materials Inter

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Layered MoO3 represents a promising cathode for aqueous rechargeable Zn‐ion batteries, but the implementation of this material is limited due to the low conductivity and poor structural stability. A 30 m ZnCl2 water‐in‐salt electrolyte (WISE) is introduced to a MoO3 nanobelt cathode for the first time, significantly increasing the stability of MoO3 cathodes compared to those in 3 m ZnSO4 and 3 m ZnCl2. The Zn/MoO3 cell in WISE unambiguously demonstrate significantly improved rate performance delivering 349, 253, and 222 mAh g−1 at 100, 500, and 1000 mA g−1, denoting a 12× capacity increase of those achieved in 3 m electrolytes at 1000 mA g−1. A capacity retention rate of 73% is achieved after (dis)charging at 100 mA g−1 for 100 cycles, and no obvious capacity fading is observed at higher current densities of 500 mA g−1 and 2 A g−1. Specifically, the data suggest that the drastic fading in 3 m electrolytes can be attributed to the parasitic surface deposits on Zn originated from Mo dissolution and H2 formation due to Zn corrosion and hydrogen evolution reaction, which are significantly suppressed in the WISE. The direct visualization of these side reactions is achieved for the first time in the Zn‐MoO3 system, using an in situ optoelectrochemical measurement.

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“…It is worth noting that it differs from the existent Scanning Kelvin Probe methodology used to follow the delamination kinetics under atmospheric conditions. Data for (b) were adapted from [27] for the Zn dissolution in 0.1 M NH 4 Cl. …”

Section: Discussionmentioning

confidence: 99%

Development of quantitative Local Electrochemical Impedance Mapping: an efficient tool for the evaluation of delamination kinetics

Shkirskiy

Volovitch

Vivier

2017

Electrochimica Acta

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To cite this version:V Shkirskiy, P Volovitch, Vincent Vivier. Development of quantitative Local Electrochemical Impedance Mapping: an efficient tool for the evaluation of delamination kinetics. Electrochimica Acta, Elsevier, 2017, 235, pp.442-452 AbstractLocal Electrochemical Impedance Mapping (LEIM) methodology was adopted to quantify the propagation of electrochemically active regions with a micrometric precision. The method consisted in the use of the gradient modulus of the admittance map as a parameter for the spatial quantification. Numerical simulations were used to optimize the experimental conditions, namely the AC frequency, the distance between the local bi-probe and the working electrode, and the distances between the probes for the local bi-probe used for the local current mapping. This analysis was reinforced by experimental verifications on coated electrodes. The quantitative LEIM methodology was successfully applied to follow the delamination kinetics on Zn coated with the polyvinyl butyral polymer in NaCl solutions. At 1 kHz, the LEIM response only reflected the position of the anodic front beneath the polymer because oxygen reduction reaction was diffusion limited and hence, independent of the applied potential. This novel LEIM methodology completes the set of usual tools used to investigate the delamination mechanisms on metal substrates.

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MoO42− as a soluble inhibitor for Zn in neutral and alkaline solutions

Cited by 34 publications

References 48 publications

Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Achieving Stable Molybdenum Oxide Cathodes for Aqueous Zinc‐Ion Batteries in Water‐in‐Salt Electrolyte

Development of quantitative Local Electrochemical Impedance Mapping: an efficient tool for the evaluation of delamination kinetics

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MoO42− as a soluble inhibitor for Zn in neutral and alkaline solutions

Cited by 34 publications

References 48 publications

Factors Affecting MoO42– Inhibitor Release from Zn2Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Factors Affecting MoO42– Inhibitor Release from Zn2Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Achieving Stable Molybdenum Oxide Cathodes for Aqueous Zinc‐Ion Batteries in Water‐in‐Salt Electrolyte

Development of quantitative Local Electrochemical Impedance Mapping: an efficient tool for the evaluation of delamination kinetics

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Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings

Factors Affecting MoO₄^2– Inhibitor Release from Zn₂Al Based Layered Double Hydroxide and Their Implication in Protecting Hot Dip Galvanized Steel by Means of Organic Coatings