Abstract:Novel mononuclear cymantrenecarboxylate complexes of transition metals, [Co(H2O)6](CymCO2)2·4H2O (Cym = (η5-C5H4)Mn(CO)3) (1), [Ni(H2O)6](CymCO2)2·4H2O (2), [Zn(H2O)6](CymCO2)2·4H2O (3), [Co(CymCO2)2(imz)2] (imz = imidazole, 4), [Co(CymCO2)2(bpy)2]·2PhMe (bpy = 2,2′-bipyridyl, 5), [Ni(CymCO2)(bpy)2(H2O)][CymCO2]·0.5MePh·2H2O (6), [Cu(CymCO2)2(imz)2] (7), and [Cu(CymCO2)2(bpy)(H2O)] (8), were obtained and characterized by single-crystal X-ray analysis. Complexes 1–3 are isostructural. Magnetism of the Co comple… Show more
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