“…However, the use of formol is hazardous as it is a carcinogenic reactant and the non-functionalization of the aliphatic chain conduct to a limited amine since the functionality is not very high, one primary amine and two secondary amines, so the aliphatic would act like a plasticizer in the epoxy resins. The thiol-ene chemistry (TEC) is a very powerful synthesis method to obtain biobased amine, like with grapeseed oil [19] or plant oils [20]. Thiol-ene reactions are the most suitable reaction for preparing these types of molecule since they can be proceeded under mild conditions including radical pathway, as thermal [21] or radiation decomposition [22], catalytic processes mediated by nucleophiles, acids, bases [23,24], or less commonly, via supramolecular catalysis in water using bcyclodextrin [25].…”