The compounds R2InO(t-Bu), R2In(acac), R2InSSiPh3, and R2InPPh2 (R = Me, CH2CMe3)
and Me2InNH(t-Bu) have been prepared in nearly quantitative yields by the cyclopentadiene
elimination reaction between R2In(C5H5) and the appropriate alcohol, thiol, phosphine or
amine. All reactions except those of H2N(t-Bu) occur readily at room temperature. Even
though solutions of R2In(C5H5) exist as equilibrium mixtures of R2In(C5H5), RIn(C5H5)2, In(C5H5)3, and InR3, neither methane nor neopentane was observed as a product from the
above reaction mixtures. A ligand redistribution reaction between Me2In(C5H5) and (Me3CCH2)2In(C5H5) was used to prepare (Me)(Me3CCH2)In(C5H5) that, in turn, was reacted with
H(acac) to form (Me)(Me3CCH2)In(acac), an indium compound with three different substituents. The compounds Me2In(acac), (Me3CCH2)2In(acac), and (Me)(Me3CCH2)In(acac) exist
as centrosymmetric dimers in the solid state, but in benzene solution Me2In(acac) is a
monomer−dimer equilibrium mixture, whereas (Me3CCH2)2In(acac) is a monomer. The
thiolate Me2InSSiPh3 is an equilibrium mixture of dimers and trimers in benzene solution,
but (Me3CCH2)2InSSiPh3 is a dimer. The phosphide Me2InPPh2 is an equilibrium mixture
of monomers and dimers when dissolved in benzene. The tert-butylamide Me2InNH(t-Bu),
when dissolved in benzene, is a mixture of monomers and dimers with both cis and trans
configurations, but only a dimer with the trans configuration exists in the solid state.