Monolayer Collapse Regulating Process of Adsorption−Desorption of Palladium Nanoparticles at Fatty Acid Monolayers at the Air−Water Interface

Abstract

In this paper, we investigate the affinity of palladium nanoparticles, stabilized with glucose oxidase, for fatty acid monolayers at the air-water interface, exploiting the interaction between a planar system and spheroids coming from the aqueous subphase. A decrease of the monolayer collapse pressure in the second cycle of interface compression proved that the presence of the nanoparticles causes destabilization of the monolayer in a mechanism driven by the interpenetration of the enzyme into the bilayer/multilayer structure formed during collapse, which is not immediately reversible after monolayer expansion. Surface pressure and surface potential-area isotherms, as well as infrared spectroscopy [polarization modulation infrared reflection adsorption spectroscopy (PM-IRRAS)] and deposition onto solid plates as Langmuir-Blodgett (LB) films, were employed to construct a model in which the nanoparticle has a high affinity for the hydrophobic core of the structure formed after collapse, which provides a slow desorption rate from the interface after monolayer decompression. This may have important consequences on the interaction between the metallic particles and fatty acid monolayers, which implies the regulation of the multifunctional properties of the hybrid material.

The Past and the Future of Langmuir and Langmuir–Blodgett Films

“…This was later confirmed with thickness measurements . Also relevant for collapse is the dissociation degree of the polar group, with the collapse characteristics changing with the pH or ions in the subphase − as well as interacting with metallic nanoparticles at the interface . For phospholipids, the formation of 3-D buds with loss of material to the subphase was proposed. − …”