Monodentate and bidentate trifluoroacetato ligands in bis(trifluoroacetato)-(N-methyl-meso-tetraphenylporphyrinato)thallium(III)—a new dynamic 4:3 piano stool seven-coordinate geometry

Yang, Chiu-Hui; Tung, Jo-Yu; Liau, Bing-Chuang; Ko, Bao‐Tsan; Elango, Shanmugham; Chen, Jyh-Horung; Hwang, Lian‐Pin

doi:10.1016/s0277-5387(01)00944-5

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Cited by 8 publications

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“…Luminol anion binds to Tl(OH) 2 þ , which is the predominant Tl(III) species at neutral pH. Supporting that, it has been reported that Tl(III) coordinates with N-containing compounds such as heme [23,24], iminophenolate [25], and a triamino-derivative of inositol [7], among others. In all these cases the average distance between Tl(III) and N atoms (2.1-2.7 Å) confers this interaction a covalent rather than ionic character.…”

Section: Resultsmentioning

confidence: 85%