Mono and oligonuclear vanadium complexes as catalysts for alkane oxidation: synthesis, molecular structure, and catalytic potential

Synthesis and kinetic studies in aqueous solution on chromium(III) complexes with isocinchomeronic acid—potential new biochromium sources

“…Usually, it forms a 5-membered chelate ring with a metal, as in picolinic acid complexes, but the presence of the 5-COOH group enables creation another single bond or a 4-membered chelate ring with the second metal ion. Numerous complexes of isocinchomeronic acid with transition metals and lanthanides were obtained from self-assembly reactions in solution [5][6][7][8][9][10][11] or by hydrothermal reaction [12][13][14][15][16][17][18] and have been characterized. Structures of some compounds were solved by singlecrystal X-ray analyses.…”

A Binuclear Copper(II) Complex Containing the Pyrazine‐2,5‐dicarboxylate Ligand: Study of the Magnetic Exchange through the Pyrazine Bridge

“…[3] Metal complexes containing pyrazine-2,5-dicarboxylate (pzdc) ligands have seldom been investigated. [4] Until now, as far as we aware, a three-dimensional Mn II complex [5] and a binuclear V V complex [6] are the only structurally characterised examples with this ligand.…”

Preparation and Structure of Double Complex Compounds [La(HMPA)4(NO3)2][Cr(NH3)2(NCS)4]

“…These precipitates were obtained during the studies of the aqueous solutions of lanthanoid (III) nitrates Ln(NO 3 4 ], (Fig.2) 9 . It was found that the symmetry of the tested sample is described by the monoclinic space group P2 1 /n, a=15.0360(3) Ǻ, b=15.1214(3) Ǻ, c=26.7529(7) Ǻ, β=100.6610(10)°, V=5977.7(9) Ǻ 3 , Z=2, =1.442 g/сm 3 .…”

“…These elements are used in computer, telecommunication and optical technologies, in radio electronics, nuclear technology and other high-tech fields [1][2][3][4][5][6][7][8] .…”