Abstract:The crystal structures of mono- and dinuclear Cu trifluoromethanesulfonate (triflate) complexes with benzyldipicolylamine (BDPA) are described. From equimolar amounts of Cu(triflate) and BDPA, a water-bound Cu mononuclear complex, aqua(benzyldipicolylamine-κN,N',N'')bis(trifluoromethanesulfonato-κO)copper(II) tetrahydrofuran monosolvate, [Cu(CFSO)(CHN)(HO)]·CHO, (I), and a triflate-bridged Cu dinuclear complex, bis(μ-trifluoromethanesulfonato-κO:O')bis[(benzyldipicolylamine-κN,N',N'')(trifluoromethanesulfonato… Show more
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