Abstract:Peak parking experiments were conducted to study the chromatographic behavior in a RPLC system consisting of a column packed with superficially porous C18-particles and a mixture of methanol and water (70/30, v/v). The values of the surface diffusion coefficient and the retention equilibrium constant of a column packed with superficially porous C18-particles were comparable to those of columns packed with a C18-silica monolith and full-porous C18-silica gel particles. The flow-rate dependence of HETP was hypot… Show more
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