Molybdenum-oxygen anionic chain grafted by Cu-phen complex. Synthesis, crystal structure and properties

Wang, Hongye; Shi, Tian; Chen, Ya Guang

doi:10.1016/j.inoche.2016.06.019

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“…Compounds 2–6 were prepared in accordance with the methods in Refs. [36–39] and characterized by the IR spectrograph and TGA.…”

Section: Methodsmentioning

confidence: 99%

Synthesis and Antibacterial Activity of Polyoxometalates with Different Structures

Zhang

Yuan

et al. 2018

Bioinorganic Chemistry and Applications

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A new inorganic-organic hybrid compound, [{Cu(phen)2}2(H4W12O40)], was synthesized, and its crystal structure was determined. The Keggin anion H4W12O40 4− was grafted with two coordination units {Cu(phen)2}, forming an electrically neutral molecule. The antibacterial activity of several polyoxometalate compounds with different anionic structures including the new compound was studied. The results show that the compound 1 can inhibit the growth of Enterococcus faecalis FA2 strains and that antibacterial activity of the polyoxometalate compounds is dependent with component elements of POM but is less relative with the anion structures.

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“…Compounds 2–6 were prepared in accordance with the methods in Refs. [36–39] and characterized by the IR spectrograph and TGA.…”

Section: Methodsmentioning

confidence: 99%