Molten Salts: Volume 4, Part 3, Bromides and Mixtures; Iodides and mixtures—Electrical conductance, density, viscosity, and surface tension data

Abstract

Data on the electrical conductance, density, viscosity, and surface tension of bromide mixtures and iodide mixtures have been systematically collected and evaluated. Results are given for eighty-five binary mixtures over a range of compositions and temperatures. Values of the above properties for twenty-three single bromide and iodide salts are also given

Liquid Metal Electrodes for Energy Storage Batteries

“…LiF-LiCl 30.5-69.5 501 [81] 2.17 --LiBr-RbBr 42-58 271 [84] 3.38 2.63 (647 °C) 1.33 (567 °C) [38] LiCl-KCl-CsCl 57.5-13.3-29.2 265 [86] 2.23 -0.28 (280 °C) [38] LiF-LiCl-LiBr 22-31-47 443 [87] 2.91 2.17-2.19 [82] 3.21 [40] LiF-LiBr-KBr 2.5-60-37.5 324 [88] 3.09 -1.56 [40] 3-63-34 312 [88] 3.12 1.75 [88] LiCl-LiBr-KBr 25-37-38 310 [89,90] 2.85 -1.7 [85] LiCl-LiBr-LiI 10.0-16.1-73.9 368 3.40 -3.68 [40] LiF-LiCl-LiI 11.7-29.1-59.2 341 [91] 3.53 2.69 [82] 2.77 [40] NaF-NaCl-NaI [20] 15 to be further improved. [106][107][108][109][110] The commercialization of longlived, liquid metal batteries rests upon the development of longlasting, and robust insulating seals.…”

“…LiI-KI 63.3-36.7 288 [83] 3.53 2.77-2.83 [84] 1.56, [40] 2.24 (607 °C) [85] LiCl-LiI 34.6-65.4 368 [81] 3.17 2.57 3.88, [40] 3.5 (450 °C)…”

Molten Salts: Volume 5, Part 2. Additional Single and Multi-Component Salt Systems. Electrical Conductance, Density, Viscosity and Surface Tension Data

“…• 134 binary mixtures with a halide salt as a component oqhe system For the preceding publications in this series see: [1][2][3][4][5][6][7][8][9]1 and table I.' [n the present work, ' .. the critical data evaluations have beeri extended to include the most complex systems, mundy, binary' systems that may include differing cations'and differing anions.…”

Electrical conductivity of CuBr in the temperature range 500–1050 K

“…The cell permitted the measurement of the conductivity of liquids as well as of solids [32,33]. A standard aqueous solution of potassium chloride (71.1352 g KCl/1000 g of solution [34,35]) was used for calibration.…”

“…have been later [35,47,52,53] fitted to these data with an accuracy estimate of 8%. While our conductivity values are generally in good agreement with those of Tubandt, the activation energy 2.28 kJ mol À 1 (Table 1) is more than twice lower than 5.92 kJ mol À 1 , the activation energy arising from the above equation.…”