Molecularly Imprinted Polymer Membranes with Photoregulated Template Binding

Minoura, Norihiko; Idei, Kazuto; Rachkov, A. E.; Uzawa, and Hirotaka; Matsuda, Kazuo

doi:10.1021/cm0305608

Cited by 39 publications

(32 citation statements)

References 19 publications

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“…Minoura and his co-workers 264,265 described the first report of P-MIP membranes containing azobenzene chromophores. MIP membranes were synthesized by using dansylamide (DA) as a template and a polymerizable derivative of azobenzene, compound 67, as the functional monomer, whilst EGDMA and tetraethylene glycoldiacrylate as crosslinkers.…”

Section: View Article Onlinementioning

confidence: 99%

Molecular imprinting: perspectives and applications

et al. 2016

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a Molecular imprinting technology (MIT), often described as a method of making a molecular lock to match a molecular key, is a technique for the creation of molecularly imprinted polymers (MIPs) with tailor-made binding sites complementary to the template molecules in shape, size and functional groups. Owing to their unique features of structure predictability, recognition specificity and application universality, MIPs have found a wide range of applications in various fields. Herein, we propose to comprehensively review the recent advances in molecular imprinting including versatile perspectives and applications, concerning novel preparation technologies and strategies of MIT, and highlight the applications of MIPs. The fundamentals of MIPs involving essential elements, preparation procedures and characterization methods are briefly outlined.Smart MIT for MIPs is especially highlighted including ingenious MIT (surface imprinting, nanoimprinting, etc.), special strategies of MIT (dummy imprinting, segment imprinting, etc.) and stimuli-responsive MIT (single/dual/ multi-responsive technology). By virtue of smart MIT, new formatted MIPs gain popularity for versatile applications, including sample pretreatment/chromatographic separation (solid phase extraction, monolithic column chromatography, etc.) and chemical/biological sensing (electrochemical sensing, fluorescence sensing, etc.). Finally, we propose the remaining challenges and future perspectives to accelerate the development of MIT, and to utilize it for further developing versatile MIPs with a wide range of applications (650 references).

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Section: View Article Onlinementioning

confidence: 99%

Molecular imprinting: perspectives and applications

et al. 2016

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“…The light converted the merocyanine into its spiropyran isomer, though the change in transport may be more due to changes in the charge state of the polymer than subtle imprinting effects-selectivity was only studied in comparison with very different substrates. An alternative photoswitchable membrane using p-phenylazoacrylanilide as switchable monomer and dansylamide as template was described more recently by Minoura et al, 1358 though only adsorption, not transport, of analytes was studied.…”

Section: Imprinted Acrylate/vinyl/acrylamide Polymers For Selective Dmentioning

confidence: 99%

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Andersson²,

et al. 2006

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Over 1450 references to original papers, reviews and monographs have herein been collected to document the development of molecular imprinting science and technology from the serendipitous discovery of Polyakov in 1931 to recent attempts to implement and understand the principles underlying the technique and its use in a range of application areas. In the presentation of the assembled references, a section presenting reviews and monographs covering the area is followed by papers dealing with fundamental aspects of molecular imprinting and the development of novel polymer formats. Thereafter, literature describing attempts to apply these polymeric materials to a range of application areas is presented.

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“…Minoura et al [150,151] described the first preparation of azo-containing MIP membranes with photo-regulated template binding properties by using a polymerizable derivate of AZB, p-phenylazoacrylanilide as the functional monomer, dansylamide as template and mixtures of tetraethylene glycol diacrylate and ethylene glycol dimethacrylate as cross-linkers. The affinity of dansylamide-specific recognition sites within these MIP membranes can reversibly be changed upon UV or visible light.…”

Section: Photo-responsive Membranes: Classes Of Adaptive Materialsmentioning

confidence: 99%

Light Responsive Polymer Membranes: A Review

et al. 2012

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In recent years, stimuli responsive materials have gained significant attention in membrane separation processes due to their ability to change specific properties in response to small external stimuli, such as light, pH, temperature, ionic strength, pressure, magnetic field, antigen, chemical composition, and so on. In this review, we briefly report recent progresses in light-driven materials and membranes. Photo-switching mechanisms, valved-membrane fabrication and light-driven properties are examined. Advances and perspectives of light responsive polymer membranes in biotechnology, chemistry and biology areas are discussed.

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Molecularly Imprinted Polymer Membranes with Photoregulated Template Binding

Cited by 39 publications

References 19 publications

Molecular imprinting: perspectives and applications

Molecular imprinting: perspectives and applications

Molecular imprinting science and technology: a survey of the literature for the years up to and including 2003

Light Responsive Polymer Membranes: A Review

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