Molecular structure and conformational properties of triflamide derivatives in the gas phase—Part II: 6‐Iodo‐3‐(triflamidomethyl)‐4‐triflyl‐1,4,2,7‐oxaazadisilepane and 2,2,4,4‐tetramethyl‐6,8‐bis (triflyl)‐3‐oxa‐6,8‐diaza‐2,4‐disilabicyclo[3.2.2]nonane by gas‐phase electron diffraction and theoretical calculations
Bagrat A. Shainyan,
Alexey V. Eroshin,
Sergey A. Shlykov
Abstract:Abstract6‐Iodo‐3‐(triflamidomethyl)‐4‐triflyl‐1,4,2,7‐oxazadisilepane 1 and the product of its cyclization, 2,2,4,4‐tetramethyl‐6,8‐bis (triflyl)‐3‐oxa‐6,8‐diaza‐2,4‐disilabicyclo[3.2.2]nonane 2, have been studied by gas‐phase electron diffraction and DFT calculations. The conformational equilibrium in the gas phase was shown to include three and two conformers for 1 and 2, respectively, in contrast to only one conformer determined by single crystal X‐ray diffraction. The structural analysis of the conformers … Show more
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