2022
DOI: 10.1088/1402-4896/ac5af1
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Molecular spin switch triggered by voltage and magnetic field: towards DNA-based molecular devices

Abstract: Spin state switching of the DNA sequences due to external stimuli is investigated theoretically. A molecular-based memory or logic device such as a spin switch could be directly realized within an electronic circuit. The DNA system is subjected an electrical potential difference through the metal leads for controling the spin transport. The spectral analysis of spin states demonstrates that voltage operates as a crucial tool to turns the switch on. The width of functional voltage range changes when the system i… Show more

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Cited by 6 publications
(7 citation statements)
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References 82 publications
(103 reference statements)
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“…The observed non-monotonous dependence denotes some reorganization in the spin-system occurring at 80–100 mT. Note that the spin-switching processes can take place in DNA, which can even be used for logical elements’ construction 19 . The decrease in the enzyme activity, in this case, was more prominent as compared to the Mg loaded samples (Fig.…”
Section: Resultsmentioning
confidence: 97%
See 1 more Smart Citation
“…The observed non-monotonous dependence denotes some reorganization in the spin-system occurring at 80–100 mT. Note that the spin-switching processes can take place in DNA, which can even be used for logical elements’ construction 19 . The decrease in the enzyme activity, in this case, was more prominent as compared to the Mg loaded samples (Fig.…”
Section: Resultsmentioning
confidence: 97%
“…To explain the magnetosensitivity of the DNA synthesis rate, some ion-radical pair should be supposed 19 , however, the problem of such a pair determination looks quite challenging and rises a lot of questions 1 . Nevertheless, the ion-radical pair providing for the magnetosensitivity of the enzymatic ATP synthesis was selected 8 .…”
Section: Resultsmentioning
confidence: 99%
“…H so is the spin-orbit coupling Hamiltonian defined as follows [30,31]: ) ] } . t so = 0.01 eV determines the spin-orbit coupling constant, θ = 0.66 rad is the helix angle and f = nΔj is the cylindrical coordinate with j = p 5 as the twist angle [32].…”
Section: Model and Methodsmentioning
confidence: 99%
“…Fe(II) spin crossover (SCO) complexes are molecules in which the strength of the octahedral ligand field surrounding the Fe atom is in the realm where even slight external perturbations, like change of temperature [1][2][3][4][5] or magnetic field, [6][7][8] can trigger a spin-state transition in these molecules. [9][10][11][12][13][14][15] At low temperatures, when the octahedral ligand field splitting (D oct ) between the t 2g and e g orbitals is high, the SCO complexes occupy the diamagnetic (S = 0) low-spin state (LS).…”
Section: Introductionmentioning
confidence: 99%