Abstract:A multicomponent ligand binds three Mn(ii) centers into a cluster that exhibits self-recognition through a diverse array of complementary intermolecular interactions, that multiply in the solid state, and seem to persist in solution.
Three chiral 3D metal–carboxylate frameworks have been successfully synthesized, featuring four-fold helical metal chains as SBUs. Co-MOFs could recognize enantio-selectively α-hydroxy/amino acids by the change of CD signals.
Three chiral 3D metal–carboxylate frameworks have been successfully synthesized, featuring four-fold helical metal chains as SBUs. Co-MOFs could recognize enantio-selectively α-hydroxy/amino acids by the change of CD signals.
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