“…As shown in studies by Bevan, there is still much to learn about crystallization dynamics, defect migration, and grain boundary fluctuations in assembled materials at the microscale, which can act as models for molecular crystal lattices. [21,22] As for the design of new materials, the reversible assembly of various types of passive particles has applications in many areas: reconfigurable structural color, polarization, or wiring devices, [23][24][25][26] structures with chirality or shape-memory, [27] and even antireflective coatings, photonic crystals, and plasmonic materials with adaptive properties. [28][29][30][31][32] While most previous studies have focused on the selfassembly of active particles into dynamic clusters or the selfassembly of passive particles using external fields, we present here a system that demonstrates the reversible autonomous assembly and defect annealing of colloidal crystals containing primarily passive particles.…”