Abstract:The molecular‐level structuration of two full photosystems into conjugated porous organic polymers is reported. The strategy of heterogenization gives rise to photosystems which are still fully active after 4 days of continuous illumination. Those materials catalyze the carbon dioxide photoreduction driven by visible light to produce up to three grams of formate per gram of catalyst. The covalent tethering of the two active sites into a single framework is shown to play a key role in the visible light activati… Show more
“…[ 109,110 ] Wisser et al. [ 111 ] reported using chromophores as light harvest antenna (controlling HOMO) and Cp*Rh as catalytic sites (regulating LUMO), which realize the rapid transfer of photogenerated charge. This kind of unique structure of long‐term stable perylene photosensitizer and the selective Rh‐based catalyst Cp*Rh@PerBpyCMP made it possible for photoreduction of CO 2 in several days.…”
Section: Recent Advances Of Other Porous Materials For Photocatalyticmentioning
confidence: 99%
“…In addition to the classic porous materials for the CO 2 photoreduction, inorganic/organic porous materials were also discussed in this section. [ 127–132 ] For the CO 2 reduction, an efficient photocatalyst should possess high uptake capacity of CO 2 . Therefore, porous carbon materials, porous metal oxides, are discussed in this section.…”
Section: Recent Advances Of Other Porous Materials For Photocatalyticmentioning
Photoreduction of CO2 into value‐added fuels is one of the most promising strategies for tackling the energy crisis and mitigating the “greenhouse effect.” Recently, metal–organic frameworks (MOFs) have been widely investigated in the field of CO2 photoreduction owing to their high CO2 uptake and adjustable functional groups. The fundamental factors and state‐of‐the‐art advancements in MOFs for photocatalytic CO2 reduction are summarized from the critical perspectives of light absorption, carrier dynamics, adsorption/activation, and reaction on the surface of photocatalysts, which are the three main critical aspects for CO2 photoreduction and determine the overall photocatalytic efficiency. In view of the merits of porous materials, recent progress of three other types of porous materials are also briefly summarized, namely zeolite‐based, covalent–organic frameworks based (COFs‐based), and porous semiconductor or organic polymer based photocatalysts. The remarkable performance of these porous materials for solar‐driven CO2 reduction systems is highlighted. Finally, challenges and opportunities of porous materials for photocatalytic CO2 reduction are presented, aiming to provide a new viewpoint for improving the overall photocatalytic CO2 reduction efficiency with porous materials.
“…[ 109,110 ] Wisser et al. [ 111 ] reported using chromophores as light harvest antenna (controlling HOMO) and Cp*Rh as catalytic sites (regulating LUMO), which realize the rapid transfer of photogenerated charge. This kind of unique structure of long‐term stable perylene photosensitizer and the selective Rh‐based catalyst Cp*Rh@PerBpyCMP made it possible for photoreduction of CO 2 in several days.…”
Section: Recent Advances Of Other Porous Materials For Photocatalyticmentioning
confidence: 99%
“…In addition to the classic porous materials for the CO 2 photoreduction, inorganic/organic porous materials were also discussed in this section. [ 127–132 ] For the CO 2 reduction, an efficient photocatalyst should possess high uptake capacity of CO 2 . Therefore, porous carbon materials, porous metal oxides, are discussed in this section.…”
Section: Recent Advances Of Other Porous Materials For Photocatalyticmentioning
Photoreduction of CO2 into value‐added fuels is one of the most promising strategies for tackling the energy crisis and mitigating the “greenhouse effect.” Recently, metal–organic frameworks (MOFs) have been widely investigated in the field of CO2 photoreduction owing to their high CO2 uptake and adjustable functional groups. The fundamental factors and state‐of‐the‐art advancements in MOFs for photocatalytic CO2 reduction are summarized from the critical perspectives of light absorption, carrier dynamics, adsorption/activation, and reaction on the surface of photocatalysts, which are the three main critical aspects for CO2 photoreduction and determine the overall photocatalytic efficiency. In view of the merits of porous materials, recent progress of three other types of porous materials are also briefly summarized, namely zeolite‐based, covalent–organic frameworks based (COFs‐based), and porous semiconductor or organic polymer based photocatalysts. The remarkable performance of these porous materials for solar‐driven CO2 reduction systems is highlighted. Finally, challenges and opportunities of porous materials for photocatalytic CO2 reduction are presented, aiming to provide a new viewpoint for improving the overall photocatalytic CO2 reduction efficiency with porous materials.
“…CNRS Silver Medal winner David Farrusseng (Université Claude Bernard Lyon 1) has been present in this section when he received the International Catalysis Award in 2016 . He was among the authors of a Research Article in Angewandte Chemie on molecular porous photosystems for photocatalytic CO 2 reduction …”
“…CNRS‐Silbermedaillengewinner David Farrusseng (Université Claude Bernard Lyon 1) wurde hier schon 2016 als Preisträger des International Catalysis Award vorgestellt . Er war unter den Autoren eines Angewandte‐Chemie ‐Forschungsartikels über molekulare poröse Systeme für die photokatalytische CO 2 ‐Reduktion …”
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