Molecular heterometallic clusters [Re_6−xMo_xS₈L₆] (x = 2–3, L = py, etpy, tbp): negligible influence of the x value on the crystal structures

Abstract

The influence of the metal ratio on the geometric characteristics and crystal structures of heterometallic clusters with {Re6−xMoxQ8} cores was studied. Complexes with the same apical ligands form isostructural packings and form the solid solutions.