A lanthanide
silylamide-catalyzed tandem reaction of isatins, diethyl
phosphite, and 2,3-diarylcyclopropenones has been developed. A series
of pyrano[2,3-b]indol-2-ones were synthesized in
high yields. The cooperation of the Lewis acidity of the lanthanide
center and the Bronsted basicity of the N(SiMe3)2 anion may be the key factor affecting the catalytic activity of
lanthanide amides.