Abstract:Lamellar membranes, especially assembled by microporous framework
nanosheets, have excited interest for fast molecular permeation.
However, the underlying molecular dissolution behaviors on membrane
surface, especially at pore entrances, remain unclear. Here,
hierarchical metal-organic framework (MOF) lamellar membranes with 7
nm-thick surface layer and 553 nm-thick support layer are prepared.
Hydrophilic (–NH2) or hydrophobic (–CH3) groups are decorated at pore
entrances on surface layer to manipulate wettabi… Show more
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