“…The TRPL of [Ru(bpy) 3 ] 2+ + {PV 4 } 2 was 6.31 µs, which was shorter than that of [Ru(bpy) 3 ] 2+ + V 2 O 5 (6.61 µs), indicating a faster electron transfer rate between [Ru(bpy) 3 ] 2+ and {PV 4 } 2 . 38,39 Without [Ru(bpy) 3 ] 2+ , {PV 4 } 2 still had a higher catalytic effect than V 2 O 5 (Fig. S15 †).…”
Section: Investigation Of the Photocatalytic Mechanismmentioning
In heterogeneous photocatalytic systems, ensuring the directed transfer of photo-generated electrons becomes key approach to enhance the utilization rate of photogenerated electrons. To accelerate the directed electron transfer, a Vanadium...
“…The TRPL of [Ru(bpy) 3 ] 2+ + {PV 4 } 2 was 6.31 µs, which was shorter than that of [Ru(bpy) 3 ] 2+ + V 2 O 5 (6.61 µs), indicating a faster electron transfer rate between [Ru(bpy) 3 ] 2+ and {PV 4 } 2 . 38,39 Without [Ru(bpy) 3 ] 2+ , {PV 4 } 2 still had a higher catalytic effect than V 2 O 5 (Fig. S15 †).…”
Section: Investigation Of the Photocatalytic Mechanismmentioning
In heterogeneous photocatalytic systems, ensuring the directed transfer of photo-generated electrons becomes key approach to enhance the utilization rate of photogenerated electrons. To accelerate the directed electron transfer, a Vanadium...
“…At present, the commonly used photosensitizers are eosin Y (EY) and its analogues, tris(2,2′-bipyridyl)ruthenium( iii ) (RuBpy) and its analogues, porphyrins and phthalocyanines. 74–80 Most of them are directly added to photocatalytic systems, while some of them are grafted onto semiconductor materials. In some cases, photocatalysts are composed of photosensitizers.…”
Section: Test System For Photocatalytic Reactionsmentioning
confidence: 99%
“…In this process, a hole will be generated, which can move to the surface of photocatalysts to drive oxidation reactions. 78–80 However, the high cost of RuBpy hinders its wide use in photocatalytic systems, and it is only widely used in the water oxidation process.…”
Section: Test System For Photocatalytic Reactionsmentioning
Prussian Blue (PB) and Prussian Blue analogues (PBAs) as coordination polymers (CPs) are excellent catalysts, which have already been widely studied in the field of electrocatalysis. A large number of...
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