Molecular composites prepared by in situ direct synthesis of wholly aromatic rigid‐rod polyamides via the phosphorylation reaction in a dissolved nylon‐6 matrix
Abstract:Wholly aromatic rigid-rod polyamides such as poly(p-phenyleneterephthalamide) (PPD-T) were synthesized in situ in a solution of nylon-6 via the phosphorylation polycondensation method to form nanocomposites or so-called "molecular composites." The incorporation of PPD-T into a nylon-6 matrix was achieved by this approach in a more compatibilized form than that obtained by the conventional coagulation method that entails precipitation of a blend of PPD-T and nylon-6 in a solvent, for example, concentrated sulfu… Show more
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