2003
DOI: 10.1039/b305699f
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Molecular arrangement of rhodamine 6G cations in the films of layered silicates: the effect of the layer charge

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Cited by 72 publications
(69 citation statements)
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“…The adsorption and following aggregation of organic dyes with RCMs has been studied extensively, especially in the presence of cationic dyes such as methylene blue [10], thionine [11], triphenylmethane dyes [12], cyanine dyes [13,14], and rhodamine dyes [15,16]. The results of these studies show that the types and amounts of dye molecular aggregates are controlled by the layer charge density of clay mineral templates.…”
Section: Introductionmentioning
confidence: 99%
“…The adsorption and following aggregation of organic dyes with RCMs has been studied extensively, especially in the presence of cationic dyes such as methylene blue [10], thionine [11], triphenylmethane dyes [12], cyanine dyes [13,14], and rhodamine dyes [15,16]. The results of these studies show that the types and amounts of dye molecular aggregates are controlled by the layer charge density of clay mineral templates.…”
Section: Introductionmentioning
confidence: 99%
“…Parallel arrangements of clay layers can be obtained by the elaboration of thin films by the spin-coating technique [96]. This parallel stacking of clay layers is confirmed by absorption spectroscopy with linearly polarized light, a well-established polarization technique extensively used to evaluate the orientation of dye molecules in clay films [85,[113][114][115]. Figure 12 shows the absorption spectra of the most dye-diluted R6G/Lap film (0.1% CEC) recorded for horizontal (H) and vertical (V) polarized light as a function of the rotation angle δ of the film around its vertical y-axis (see experimental set-up in Fig.…”
Section: Dye Orientation In Ordered Clay Films a Fluorescence Anisotmentioning
confidence: 99%
“…Moreover, the immobilization of photoactive guest molecules with a preferential arrangement in organized nanostructured inorganic networks can lead to a macroscopic alignment of photofunctional molecules with interesting applications in nonlinear optics [1,[9][10][11].…”
Section: Introductionmentioning
confidence: 99%