Molecular And Solid‐State Structure Of Oxovanadium(IV) Etioporphyrin‐III
Georgy L. Pakhomov,
Andrey I. Koptyaev,
Pavel A. Yunin
et al.
Abstract:Oxovanadium(IV) etioporphyrin‐III, VO‐EtioP‐III is an important member of the petroporphyrin family. It can be isolated from crude oil or synthesized de novo from the dipyrromethene precursors, the latter being the approach we used in our research. The molecular structure of VO‐EtioP‐III was for the first time characterized by single‐crystal X‐ray diffraction. Both terminal alkyls and the axial oxygen atom protrude in the same direction relative to the molecular plane, while rear side of the molecule remains a… Show more
“…22 Another type of oxovanadium compounds that may have potential applications in some form in computing are vanadyl porphyrins. 23 These vanadium( iv ) complexes (see, a crystal structure of a synthetic vanadyl petroporphyrin 24 ) were detected e.g. in Venezuela Orinoco heavy crude oil by using Fourier transform-ion cyclotron resonance mass spectrometry 25 or could be extracted from oil of the North Buzachi oil-and-gas-bearing region in Kazakhstan.…”
Vanadium is a critical raw material. In the nearby future, it may, however, become one of the key elements of computer devices based on two-dimensional arrays of spin qubits for...
“…22 Another type of oxovanadium compounds that may have potential applications in some form in computing are vanadyl porphyrins. 23 These vanadium( iv ) complexes (see, a crystal structure of a synthetic vanadyl petroporphyrin 24 ) were detected e.g. in Venezuela Orinoco heavy crude oil by using Fourier transform-ion cyclotron resonance mass spectrometry 25 or could be extracted from oil of the North Buzachi oil-and-gas-bearing region in Kazakhstan.…”
Vanadium is a critical raw material. In the nearby future, it may, however, become one of the key elements of computer devices based on two-dimensional arrays of spin qubits for...
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