Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand

Tu, Xinhui; Trương, Hoàng Lê; Nichol, Gary S.; Zheng, Zhiping

doi:10.1016/j.ica.2010.06.063

Inorganica Chimica Acta

2010

DOI: 10.1016/j.ica.2010.06.063

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Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand

Xinhui Tu¹,

Hoàng Lê Trương²,

Gary S. Nichol³

et al.

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Cited by 10 publications

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Mononuclear Transition Metal Complexes of 7‐Nitro‐1,3,5‐Triazaadamantane

Wagner

Coles

2016

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Abstract:Complexes of the type [MCl2(7-nitro-1,3,5-triaza-adamantane)2] (M = Zn(II), Pd(II), Pt(II)) and [MCl2(H2O)2(7-nitro-1,3,5-triazaadamantane)2] (M = Mn (II), Co(II), Ni(II)) have been prepared and their structures have been analysed by X-ray crystallography, elemental analysis, IR and solid state 13 C and 15 N NMR spectroscopy, supported by density functional theory/gauge independent atomic orbital (DFT/GIAO) calculations. In each case, 7-nitro-1,3,5-triazaadamantane acts as a mono-dentate ligand and binds to one metal centre only, in spite of the presence of three equivalent amino nitrogens. In the Co(II) and Ni(II) complexes, a two-dimensional intermolecular hydrogen bonding network between the aqua-and the chloro ligands is established. The uncoordinated amines of the 7-nitro-1,3,5-triaza-adamantane are not involved in any Hbonding, as a result of the exceptionally low basicity of this compound.

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Mononuclear Transition Metal Complexes of 7‐Nitro‐1,3,5‐Triazaadamantane

Wagner

Coles

2016

ChemistrySelect

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Hexamethylenetetramine: An old new building block for design of coordination polymers

Kirillov¹

2011

Coordination Chemistry Reviews

165

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Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications

Guerriero

Peruzzini

Gonsalvi

2018

Coordination Chemistry Reviews

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Molecular and polymeric Hg(II) complexes with a PTA (1,3,5-triaza-7-phosphaadamantane) complex of the [Re6(μ3-Se)8]2+ core-containing cluster as ligand

Cited by 10 publications

References 59 publications

Mononuclear Transition Metal Complexes of 7‐Nitro‐1,3,5‐Triazaadamantane

Mononuclear Transition Metal Complexes of 7‐Nitro‐1,3,5‐Triazaadamantane

Hexamethylenetetramine: An old new building block for design of coordination polymers

Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: Novel architectures, materials and applications

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