There is a clear trend in industry to eliminate fluorine from metallurgical slags. Regarding the continuous casting process, fluorine in mould powders is undesirable due to the following reasons: (i) evolves easily from slags producing health-injurious gaseous substances like hydrofluoric acid, (ii) creates problems for storage and utilization of solid waste, and (iii) causes machinery corrosion. A collaboration among universities, mould powder supplier, and steel producer was established, aiming for the development of a new F-free mould powder for billet casting. Firstly, technological parameters for a particular composition were determined: melting characteristics, viscosity, melting behavior, and crystallization tendency. Afterwards, industrial trials were performed in a Brazilian steelworks, doing some evaluations during the continuous casting process, such as DT between water cooling inlet and outlet, slag pool thickness, melting performance, powder consumption, Al 2 O 3 pick-up, and effect on SEN erosion. Comparable surface quality for the billets was obtained when using the F-free mould powder, since the amount of scrap produced during the rolling process was not critical.