Molar conductivity behavior of ionic liquid compare to inorganic salt in electrolyte solution at ambien temperature

Limiting Molar Conductivity Dynamics of κcar/PEO/NaClO4 Aqueous Electrolyte System at Different Temperature

“…The fluctuation in κ observed is beyond the sensitivity capability of the probe. However, it is believed that this region will not affect our calculations and interpretations of the graph [25].…”

“…7, we can obtain Cref value. It is obtained that the Cref value for NaClO4 at 25 ºC is approximately two times lower than the lowest Csalt value that follows linearity in Power law graph as suggested by Hanibah [25]. Therefore, a backwards calculation is done to determine the Λo of a system.…”

“…Determination of Λ Λ Λ Λ Λ o of NaClO 4 in deionized water after power law at 20 ºC and 25 ºC: As a result of strong thermodynamic hydration interaction between salt and water, NaClO 4 undergoes full dissociation, yielding a high concentration of free moving ions, particularly at dilute condition where the C salt is less than 1.0 × 10 -4 mol cm -3 as shown in eqn. 1 [25]: NaClO4 (aq.) → Na + (aq.)…”

“…However, the instrument such as conductivity meter has measurement limitation. Therefore, an alternative approach as suggested by Hanibah [25] named as Power law will be applied in order to obtain the Λo.…”

Salicylate-Based Ionic Liquids as Innovative Ingredients in Dermal Formulations

“…The L m,0 of inorganic salts is considerably lower and is usually between 100 and 200 S¢cm 2 ¢mol À1 . 24 For some conventional ILs, even L m,0 below 100 are reported, for example, [BA][Sal] with 68.31 S¢cm 2 ¢mol À1 in water at 25°C. 25 Based on the literature data, the theoretical L m,0 of benzalkonium cation and [BA][Cl] could be calculated (Table 3), and based on the data, the degree of dissociation was determined (Table 1 supplemented data).…”