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Polyamide exhibits hygroscopic nature and can absorb up to 10 % of moisture relative to its weight. The absorbed moisture increases the mobility of the molecular chains and causes a reduction in the glass transition temperature. Thus, depending on the moisture distribution, a polyamide component can show different stiffness and relaxation times. The moisture distribution also depends on the mechanical loading of the material. However, it was noticed that the diffusion process remains unaffected when the process is compared for a loaded and an unloaded material. It is postulated that the moisture redistribution is due to an external force that takes place as a result of the pressure acting on the moisture. The diffusion process is unaffected by preloading of the dry material as the pressure is applied purely on the material and not on the absorbed moisture. However, when a saturated specimen is loaded, the pressure is exerted on the moisture too which causes its redistribution. In this work, the distribution of the absorbed moisture is simulated by a non-linear diffusion model. It is coupled with the viscoelastic behaviour of PA6. The stiffness of the viscoelastic model changes and the relaxation time reduces with increasing moisture concentration. The coupling of diffusion to mechanical loading is achieved with the recalculation of the moisture concentration caused due to the redistribution of volume. It is assumed that there is no transport of moisture, but the transport of volume and the change in volume creates a change in concentration in the specimen. This strongly coupled model has been implemented using the finite element method. The model results are compared to experiments for validation. A strongly coupled model was thus created which could reproduce the experimental results with reasonable accuracy.
Polyamide exhibits hygroscopic nature and can absorb up to 10 % of moisture relative to its weight. The absorbed moisture increases the mobility of the molecular chains and causes a reduction in the glass transition temperature. Thus, depending on the moisture distribution, a polyamide component can show different stiffness and relaxation times. The moisture distribution also depends on the mechanical loading of the material. However, it was noticed that the diffusion process remains unaffected when the process is compared for a loaded and an unloaded material. It is postulated that the moisture redistribution is due to an external force that takes place as a result of the pressure acting on the moisture. The diffusion process is unaffected by preloading of the dry material as the pressure is applied purely on the material and not on the absorbed moisture. However, when a saturated specimen is loaded, the pressure is exerted on the moisture too which causes its redistribution. In this work, the distribution of the absorbed moisture is simulated by a non-linear diffusion model. It is coupled with the viscoelastic behaviour of PA6. The stiffness of the viscoelastic model changes and the relaxation time reduces with increasing moisture concentration. The coupling of diffusion to mechanical loading is achieved with the recalculation of the moisture concentration caused due to the redistribution of volume. It is assumed that there is no transport of moisture, but the transport of volume and the change in volume creates a change in concentration in the specimen. This strongly coupled model has been implemented using the finite element method. The model results are compared to experiments for validation. A strongly coupled model was thus created which could reproduce the experimental results with reasonable accuracy.
In this contribution, a numerical calculation environment for the determination of the moisture absorption of polyamide 6 (PA 6) is developed. The focus in this context is on modeling and evaluating the influence of locally varying water concentrations and existing moisture gradients on the mechanical properties of the material. Defined moisture distributions are set by specific conditioning processes and compared to the results of an FE calculation environment. The developed numerical method combines a mass diffusion with a subsequent structural‐mechanical simulation. The first includes a transient analysis of moisture absorption and the resulting swelling processes and residual stresses. The water concentration and residual stress distributions determined within this calculation are implemented as initial conditions in the structural mechanics FE analysis. The experimental setup of the three‐point bending test is considered in this case. The evaluation of the moisture‐induced influence on the mechanical behavior of the considered PA 6 is performed using a linear elastic modeling approach. The validation and evaluation of the calculation quality is carried out for the sorption and swelling calculation as well as for the FE model by means of experimental test data. The calculation methodology presented in this work provides a novel and even more accurate approach for the design of plastic components which are exposed to the influence of environmental humidity or direct water contact in their application.
Polyamide exhibits hygroscopic nature and can absorb up to 10% of moisture relative to its dry weight. The absorbed moisture increases the mobility of the molecular chains and causes a reduction in the glass transition temperature. Thus, depending on the moisture distribution, a polyamide component can show different stiffness and relaxation times. Moreover, the moisture distribution also depends on the mechanical loading of the material as the volumetric deformation results in a change of the available free volume for the moisture. Thus, a strongly coupled model is required to describe the material behaviour. In this work, a thermodynamically consistent coupled model within the framework of mixture theory is developed. The mechanical deformation of polyamide 6 (PA6) is based on a linear viscoelastic material model, and the moisture transport is based on a nonlinear diffusion model. The stiffness and the relaxation time of the viscoelastic model change with the moisture concentration. Furthermore, the moisture transport is affected by the pressure gradient generated by the mechanical loading of the material. This strongly coupled model has been implemented using the finite element method, and simulation results are presented for a three-point bending experiment.
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