MOF-derived FeF2 nanoparticles@graphitic carbon undergoing in situ phase transformation to FeF3 as a superior sodium-ion cathode material

Maulana, Achmad Yanuar; Futalan, Cybelle M.; Kim, Jongsik

doi:10.1016/j.jallcom.2020.155719

Cited by 30 publications

(23 citation statements)

References 58 publications

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“…FeF 2 @GC exhibited augmented cycling stability, associated with a reversible capacity of 120.5 mA h g À1 over 300 cycles at 50 mA g À1 . 139 The performance of some more MOF-based cathodes for Na-ion battery has been listed in Table 2. 83,95,96,[140][141][142][143][144][145][146] As reported by Goodenough and co-workers, Prussian blue KFeFe(CN) 6 was observed to be quite stable, possessing an open framework in carbonate electrolyte during Na + insertion/ de-insertion.…”

Section: Mof As Cathode Materials For Various Energy Storage Modesmentioning

confidence: 99%

Metal–organic framework-based materials: advances, exploits, and challenges in promoting post Li-ion battery technologies

et al. 2021

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Section: Mof As Cathode Materials For Various Energy Storage Modesmentioning

confidence: 99%

Metal–organic framework-based materials: advances, exploits, and challenges in promoting post Li-ion battery technologies

et al. 2021

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“…32 Similar to the fact that fewer MOF derivatives are reported as cathodes for LIBs, there are also relatively few works of MOF derivatives as cathodes for SIBs. 58 Nonetheless, it is worth noting that MOF-derived carbon-based materials are increasingly used as anodes for potassium-ion batteries, another promising alternative to LIBs. 59 LSBs.…”

Section: Applications In Various Eesc Systemsmentioning

confidence: 99%

“…Benefiting from the unique shell configuration and complex composition, the Cu-CoS 2 @Cu x S DSNBs show outstanding rate capability with a capacity of 515 and 333 mAh g –1 at a current density of 0.1 and 5.0 A g –1 , respectively (Figure f) . Similar to the fact that fewer MOF derivatives are reported as cathodes for LIBs, there are also relatively few works of MOF derivatives as cathodes for SIBs . Nonetheless, it is worth noting that MOF-derived carbon-based materials are increasingly used as anodes for potassium-ion batteries, another promising alternative to LIBs …”

Section: Applications In Various Eesc Systemsmentioning

confidence: 99%

Metal–Organic Frameworks Derived Functional Materials for Electrochemical Energy Storage and Conversion: A Mini Review

et al. 2021

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With many apparent advantages including high surface area, tunable pore sizes and topologies, and diverse periodic organic−inorganic ingredients, metal−organic frameworks (MOFs) have been identified as versatile precursors or sacrificial templates for preparing functional materials as advanced electrodes or high-efficiency catalysts for electrochemical energy storage and conversion (EESC). In this Mini Review, we first briefly summarize the material design strategies to show the rich possibilities of the chemical compositions and physical structures of MOFs derivatives. We next highlight the latest advances focusing on the composition/structure/performance relationship and discuss their practical applications in various EESC systems, such as supercapacitors, rechargeable batteries, fuel cells, water electrolyzers, and carbon dioxide/nitrogen reduction reactions. Finally, we provide some of our own insights into the major challenges and prospective solutions of MOF-derived functional materials for EESC, hoping to shed some light on the future development of this highly exciting field.

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“…[152] An obvious 2D-band peak can be observed in the Raman spectrum of the MOF-derived carbon. Meanwhile, the characteristic graphitic XRD peak is much sharper than that of commercial activated carbon, implying the high graphitization ZIF-67 N C V 2 O 5 @C 147@ 1 C, 75.7%@800@5 C LIBs [136] MIL-47(V) V C V 2 O 5 @C 218.1@1 C, 91%@50@0.1 C LIBs [137] V-MOF V C LVP/P-C 65@10 C, 90%@1100@10 C LIBs [138] MIL-101(V) V C LVP@C 144.4@0.1 C, 81%@1000@0.5 C LIBs [139] MnNi-BDC Mn Ni LNMO 121.4@1 C, 83.8%@500@20 C LIBs [140] Fe HKUST-1(Cu) Cu C C@Cu 1.96 S 231@0.2 C, 94%@50@ 0.1 C LIBs [145] NiMn-PMA Ni Mn LNMO 145@0.1 C, 78.7%@500@10 C LIBs [146] NiMn-MOF Ni Mn LNMO 145.3@1 C, 96.9%@500@1 C@40 °C LIBs [147] ZIF-67 Co C LCO@N-C 150.3@10 C,89.1%@200@1 C LIBs [148] ZIF-67 Co LCO 123@0.5 C, 96.4%@100@2 C LIBs [149] ZIF-67 Co LCO/Au foam 155.4@0.2 C, 78.4%@600@2 C LIBs [150] ZIF-4(Co) Co Na 0.74 CoO 2 /C/N 107@0.1 C, 97%@50@5 C SIBs [151] CoZn-ZIF N C NVP@N-C 117@1 C, 87%@10 000@100 C SIBs [152] MIL-101(V) V C NVP@C 136.4@1 C, 84.2%@1000@5 C SIBs [153] ZIF-67 N C NVP/C -, 86.3%@5000 @20 C SIBs [154] V-MOF V C NVP/N-C 117.3@0.1 C, 84%@500@10 C SIBs [155] MIL-125 Ti NTP/rGO 129.2@0.1 C, 91%@250@0.5 C SIBs [156] Fe-MIL-88B Fe C FeOF/C 437.3@0.1 A g −1 , 78%@100@0.1 A g −1 SIBs [157] Fe-MIL-88B Fe C FeF 2 @GC 304.2@50 mA g −1 , 59%@1000@0.3 A g −1 SIBs [158] ZIF-8 N C Mn x O@N-C 192%@120@100 mA g −1 ZIBs [39] MOF-74(Mn) Mn Mn 3 O 4 396.2@0.2 A g −1 , 95.7%@12 000@5 A g −1 ZIBs [159] MnAl-BTC Mn Al Mn 2 O 3 /Al 2 O 3 -, 147.5%@1100@1.…”

Section: Mofs As a Carbon Sourcementioning

confidence: 99%

Metal/Covalent‐Organic Framework Based Cathodes for Metal‐Ion Batteries

Kong

Liu

Huang

et al. 2021

Advanced Energy Materials

165

102

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world's energy system from non-renewable fossil energy to low-carbon and multienergy fusion. How to fully develop and efficiently utilize clean energy to achieve carbon emission reduction has become a common concern of all countries around the world. In recent years, highly efficient electrochemical energy storage devices have attracted more attention and significantly impacted on scientific and industrial communities. [1] They can execute intermittent power storage and release, unrestricted by the geographical terrain, and can be directly applied to practical demands, such as electric vehicles, large-scale energy storage, and micro-devices. Currently, hundreds of electrochemical energy storage devices have been developed, exhibiting different technical mechanisms and application spaces. [2] Supercapacitors dominate the field of high power applications, while rechargeable metal-ion batteries such as lithium-ion batteries (LIBs) and next-generation metal-ion batteries (low-cost and abundant potassium, sodium, magnesium, zinc, and aluminum battery systems) are expected to govern high energy density applications. [3][4][5] During the discharge process, positive ions migrate from the anode into the cathode and generate electrons, while the charging process is the opposite. [6] During this reversible process, electrode materials are the core components in metal-ion batteries and the main substances in an electrochemical redox reaction and their physical and chemical properties closely correspond to the performance of electrochemical energy storage equipment in either electrolytic or galvanic cell systems. Therefore, developing novel, highly active, multifunctional electrode materials has become a key issue in achieving efficient energy storage and conversion. [7] Currently, cathode materials occupy the most important position in the composition of metal-ion batteries. [8] The properties of cathode materials directly determine the final performance indexes of metal-ion battery products. [9] Moreover, in commercial LIB devices, cathode materials account for about 40% of the cost of the whole cell. [10] However, compared with the fast-developing development of anode materials, the development of cathode materials has been relatively slow. One reason is that it is challenging to prepare highly crystalline cathodes, and even slight changes in the preparation process can lead to great differences in material structures and properties. Another factor is that cathode materials present a low specific capacity relative to anode materials, which directly influences the energy density Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs) are two emerging families of functional materials used in many fields. Advantages of both include compositional designability, structural diversity, and high porosity, which offer immense possibilities in the search for high-performance electrode materials for metal-ion batteries. A large number of MOF/COF-based cathode materials have been reported. Despite these advantageous fea...

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MOF-derived FeF2 nanoparticles@graphitic carbon undergoing in situ phase transformation to FeF3 as a superior sodium-ion cathode material

Cited by 30 publications

References 58 publications

Metal–organic framework-based materials: advances, exploits, and challenges in promoting post Li-ion battery technologies

Metal–organic framework-based materials: advances, exploits, and challenges in promoting post Li-ion battery technologies

Metal–Organic Frameworks Derived Functional Materials for Electrochemical Energy Storage and Conversion: A Mini Review

Metal/Covalent‐Organic Framework Based Cathodes for Metal‐Ion Batteries

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