MOF-Derived Cobalt Nanoparticles with Dispersed Iron Phthalocyanines as Bifunctional Oxygen Electrocatalysts
Jie Liu,
Qiuhong Sun,
Qiu Ye
et al.
Abstract:Iron phthalocyanine (FePc), characterized by its distinctive Fe−N 4 sites, represents a macromolecular catalyst with promising applications in bifunctional oxygen catalysis. However, its inherently flat and symmetrical configuration often results in relatively weak electrocatalytic performance. In this study, a novel approach was employed by first anchoring the Co-based zeolitic imidazolate framework onto microsized carbon spheres derived from a Zn-based coordination polymer, followed by the incorporation of d… Show more
Modulating the local electronic structure in 3d transition metal oxides is appealing in N2 reduction reaction (NRR), yet remains challenging. Herein, Ni dopants with higher electronegativity are introduced to tune...
Modulating the local electronic structure in 3d transition metal oxides is appealing in N2 reduction reaction (NRR), yet remains challenging. Herein, Ni dopants with higher electronegativity are introduced to tune...
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