MOF catalysts in biomass upgrading towards value-added fine chemicals

Herbst, Annika; Janiak, Christoph

doi:10.1039/c6ce01782g

Cited by 197 publications

(133 citation statements)

References 170 publications

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“…Due to the immense quantity of possible inorganic and organic building units several applications are discussed (e.g., gas storage and separation, catalysis, sensing and heat transformation) [1][2][3][4][5][6][7][8][9][10][11][12][13]. Many different organic functionalities have been introduced into the frameworks either by a priori ligand functionalization or by post synthetic modification [14][15][16].…”

Section: Introductionmentioning

confidence: 99%

Incorporating the Thiazolo[5,4-d]thiazole Unit into a Coordination Polymer with Interdigitated Structure

2018

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Abstract:The linker 2,5-di(4-pyridyl)thiazolo [5,4-d]thiazole (Dptztz), whose synthesis and structure is described here, was utilized together with benzene-1,3-dicarboxylate (isophthalate, 1,3-BDC 2− ) for the preparation of the two-dimensional coordination network [Zn(1,3-BDC)Dptztz]·DMF (DMF = dimethylformamide) via a solvothermal reaction. Compound [Zn(1,3-BDC)Dptztz]·DMF belongs to the class of coordination polymers with interdigitated structure (CIDs). The incorporated DMF solvent molecules can be removed through solvent exchange and evacuation such that the supramolecular 3D packing of the 2D networks retains porosity for CO 2 adsorption in activated [Zn(1,3-BDC)Dptztz]. The first sorption study of a tztz-functionalized porous metal-organic framework material yields a BET surface of 417 m 2 /g calculated from the CO 2 adsorption data. The heat of adsorption for CO 2 exhibits a relative maximum with 27.7 kJ/mol at an adsorbed CO 2 amount of about 4 cm 3 /g STP, which is interpreted as a gate-opening effect.

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Section: Introductionmentioning

confidence: 99%

Incorporating the Thiazolo[5,4-d]thiazole Unit into a Coordination Polymer with Interdigitated Structure

2018

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“…A possible industrial application of MOFs could be as catalysts for the transformation of biomass to value added chemicals . This is a relatively new area gaining popularity in a sustainable, green, and circular carbon economy.…”

Section: Figurementioning

confidence: 99%

“…Ap ossible industrial application of MOFs could be as catalysts for the transformation of biomass to value added chemicals. [44] This is ar elatively new area gaining popularity in as ustainable,g reen, and circular carbon economy.E ven though MOFs are,i ng eneral, moisture-sensitive,t here are af ew hydrolytically stable MOF catalysts which show promise.A cid catalysis is generally preferred in biomass depolymerisation and molecular reactions because bases produce intractable emulsions with water. Then umber of Brønsted acid MOFs is,h owever, limited.…”

Section: Framework Solidsmentioning

confidence: 99%

Crystal Engineering: An Outlook for the Future

2019

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Crystal Engineering has traditionally dealt with molecular crystals. It is the understanding of intermolecular interactions in the context of crystal packing and in the utilization of such understanding in the design of new solids with desired physical and chemical properties. We outline here five areas which come under the umbrella of Crystal Engineering and where we feel that a proper planning of research efforts could lead to higher dividends for science together with greater returns for humankind. We touch on themes and domains where science funding and translation efforts could be directed in the current climate of a society that increasingly expects applications and utility products from science and technology. The five topics are: 1) pharmaceutical solids; 2) industrial solid state reactions; 3) mechanical properties with practical applications; 4) MOFs and COFs framework solids; 5) new materials for solar energy harvesting and advanced polymers.

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“…In fact, there are three thematic reviews of the field; some of the most recent studies, that is, the topic of this Minireview, are listed in Table . Owing to the ease with which MOFs can be strategically designed, they have since gained a prominent reputation among heterogeneous catalysts ,–,,…”

Section: Functionalizing Mofs For Organic Transformationsmentioning

confidence: 99%

Recent Advances of MOFs and MOF‐Derived Materials in Thermally Driven Organic Transformations

Yang

Bulut

et al. 2018

Chemistry A European J

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Owing to the almost boundless structural tunability, MOF and MOF-derived catalysts have recently exhibited structures of higher complexity, and hence, have demonstrated activity in a wide array of organic transformations. These reactions have a broad range of important applications ranging from pharmaceuticals to agriculture. Given the increasing number of publications in the area, this Minireview is focused on the most recent advancements in thermally driven organic transformations using both MOFs, nanoparticle@MOF (NP@MOF) composites, and several classes of MOF-derived materials. The most recent advancements made in materials design and the utility of these materials in a broad range of reactions are discussed.

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MOF catalysts in biomass upgrading towards value-added fine chemicals

Cited by 197 publications

References 170 publications

Incorporating the Thiazolo[5,4-d]thiazole Unit into a Coordination Polymer with Interdigitated Structure

Incorporating the Thiazolo[5,4-d]thiazole Unit into a Coordination Polymer with Interdigitated Structure

Crystal Engineering: An Outlook for the Future

Recent Advances of MOFs and MOF‐Derived Materials in Thermally Driven Organic Transformations

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