Modulation of the Structural, Magnetic, and Dielectric Properties of YMnO3 by Cu Doping

Abstract

The lower valence compensation of YMn1-xCuxO3 (x = 0.00, 0.05, and 0.10) is prepared by the solid-state reaction, and the effects of divalent cation Cu-doping on the construction and magnetic and dielectric attributes of multiferroic YMnO3 are systemically researched. Powder X-ray diffraction shows YMn1-xCuxO3 has a single-phase hexagonal construction with a P63cm space group as the parent YMnO3, and lattice parameters decrease systematically as Cu concentration increases. Using the scanning electric microscope, structure morphologies analysis shows that the mean grain size varies between 1.90 and 2.20 μm as Cu content increases. YMn1-xCuxO3 magnetization increases as Cu doping concentration increases, and the antiferromagnetic transition temperature declines from 71 K for x = 0.00 to 58 K for x = 0.10. The valence distributions of Mn ions conduce to the modified magnetic attributes. Due to Cu substitution, the dielectric loss and dielectric constant decline as frequency increases from 400 to 700 K, showing representative relaxation behaviors. Indeed, that is a thermally activated process. In addition, the peak of the dielectric loss complies with the Arrhenius law. The relaxation correlates to the dipole effect regarding carrier hopping between Mn3+ and Mn4+, and also correlates to oxygen vacancies generated by Mn2+.