A benchmark for the validation of solidification modelling algorithms E Kaschnitz, S Heugenhauser and P Schumacher -Influence of forced convection on solidification and remelting in the developing mushy zone M Wu, A Vakhrushev, A Ludwig et al. Abstract. The influence of alloying elements (Cu, Mg, and Ni) on eutectic nucleation, eutectic grain morphology and the final microstructure of an Al-10Si commercial purity alloy in unmodified and Sr-modified conditions was investigated. It was found that the nucleation and eutectic grain growth morphologies of both the unmodified and Sr-modified Al-Si eutectic were significantly influenced by the addition of ternary alloying elements to a degree dependent on when the intermetallic phase formed during the solidification of the alloy with respect to the Al-Si eutectic. In cases where an intermetallic phase nucleated prior to the onset of the Al-Si eutectic reaction, the eutectic nucleation frequency was affected by changes to the available nuclei population. In cases where the intermetallic nucleated after the Al-Si eutectic, segregation of the ternary solutes in front of the Al-Si eutectic interface changed the nucleation and macroscopic growth dynamics. The changes in nucleation and growth dynamics of the Al-Si eutectic due to the presence of solute altered the morphology of the eutectic silicon considerably. This study has revealed a number of insights into the mechanisms of nucleation and growth of the Al-Si eutectic.
IntroductionMany commercial hypo-eutectic Al-Si alloys contain 5-12wt.%Si [1]. Cu and Mg are often added to achieve strengthening [1,2]. Recent research has shown that changes in the nucleation frequency and macroscopic evolution of the Al-Si eutectic influence the final microstructure and formation of casting defects [3][4][5][6]. Impurity modification, alloy purity, the presence of solute and the solidification conditions are some of the factors that can influence eutectic nucleation, macroscopic growth patterns and the scale and morphology of the microstructure [7][8][9]. However, with the exception perhaps of the modifying elements Sr, Na and Sb, the influence of common alloying elements on eutectic nucleation and the macroscopic evolution of the eutectic phases in Al-Si alloys are relatively unexplored. The solidification of a binary hypo-eutectic Al-Si alloy starts with the nucleation and growth of Al dendrites followed by the nucleation and growth of the Al-Si eutectic phases. It is reasonable to assume that the addition of a ternary alloying element will influence the number and distribution of nuclei present in the melt. In addition, solute pile-up ahead of both the primary Al phase and the eutectic growth interface can create constitutionally supercooled (CS) zones [10] which will influence both nucleation and growth. The purpose of this work is to investigate the influence of alloying elements (Cu, Mg and Ni) on eutectic nucleation, grain morphology and the final microstructure.