Modification of Surface of Carbon Fiber Materials by Plasma Treatment (Review)

Sidorina, A. I.; Imametdinov, E.Sh.

doi:10.1007/s10692-020-10159-w

Cited by 8 publications

(4 citation statements)

References 18 publications

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“…Another field of study on what is defined as bulk modification is improving interfacial adhesion with fibers in composites. Extensive research has been done into the plasma treatment of natural [136,137] and carbon [138][139][140][141][142][143] fibers, but the literature is sparse in plasmamodified polymers for this application.…”

Section: Plasma As a Polymer Bulk Modification Methodsmentioning

confidence: 99%

A review of polymer surface modification by cold plasmas toward bulk functionalization

Bertin,

Leitao,

Bickerton

et al. 2024

Plasma Processes & Polymers

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Plasma surface modification of polymers is a well‐established method applied to increase the surface energy of these materials, where the capacity of cold plasmas to generate free radicals and functionalize the surface with polar groups is widely reported in the literature. This article provides a comprehensive literature review on plasma surface treatment, plasma‐induced grafting, and plasma polymerization, evaluating how these techniques can be applied to modify the bulk properties of polymers. A novel process of plasma‐induced polymer bulk functionalization in the melt state is introduced, where an atmospheric pressure plasma jet could be applied to a continuous reactive extrusion process, enhancing the production of graft copolymers for compatibilization of polymeric blends and fiber composites.

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Section: Plasma As a Polymer Bulk Modification Methodsmentioning

confidence: 99%

A review of polymer surface modification by cold plasmas toward bulk functionalization

Bertin,

Leitao,

Bickerton

et al. 2024

Plasma Processes & Polymers

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“…An alternative method for increasing adhesion in polymer laminates is CF surface treatment with cold plasma [ 30 , 31 , 32 , 33 ]. In this method, it interacts with ions, free electrons, excited atoms and molecules, as well as radicals, increasing the free energy and forming active polar groups [ 34 , 35 , 36 ]. In addition, microroughness increases on the surface of CFs upon plasma treatment, which, according to the mechanical interlocking theory [ 37 , 38 , 39 ], contributes to an additional increase in adhesion between fibers and polymers [ 40 , 41 ].…”

Section: Introductionmentioning

confidence: 99%

Structure and Deformation Behavior of Polyphenylene Sulfide-Based Laminates Reinforced with Carbon Fiber Tapes Activated by Cold Atmospheric Plasma

Kosmachev,

Panin,

Panov

et al. 2023

Polymers

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Low-temperature plasma treatment with atmospheric discharge with runaway electrons (DRE) was shown to be an efficient way to activate carbon fiber’s (CF) surface and subsequently increase its interlayer shear strength (ILSS) values. It was demonstrated that an acceptable ILSS level was achieved after a DRE plasma treatment duration of 15 min. The treatment of CFs resulted in their surface roughness being increased and their functional groups grafting. The XPS data showed a change in the chemical composition and the formation of reactive oxygen-containing groups. SEM examinations of the PPS/CF laminates clearly demonstrated a difference in adhesive interaction at the PPS/CF interface. After the DRE plasma treatment, CFs were better wetted with the polymer, and the samples cohesively fractured predominantly through the matrix, but not along the PPS/CF interface, as was observed for the sample reinforced with the untreated CFs. The computer simulation results showed that raising the adhesive strength enhanced the ILSS values, but reduced resistance to transverse cracking under the loading pin. In general, higher flexural strength of the PPS/CF laminates was achieved with a greater interlayer adhesion level, which was consistent with the obtained experimental data.

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“…Therefore, enhancing the interface performance of CF composite has always been a hot issue of research 8–10 . At present, the interface modification methods of CF composite are as follows: (1) Chemical vapor deposition 11,12 is to produce chemical reactions and transport reactions of gaseous substances on solids at medium or high temperatures. (2) Chemical grafting method 13,14 is the method of chemical reaction to graft organic molecules or nanoparticles.…”

Section: Introductionmentioning

confidence: 99%

Study on the enhancement of the interface performance between CF and polyimide by triethylamine grafting nano‐TiO₂ particles

Li¹

2021

Surface & Interface Analysis

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The TiO2 is grafted by triethylamine and is introduced on the surface of the carbon fiber, which improves the wettability and activity of the carbon fiber surface and at the same time strengthens the carbon fiber/polyimide composite. Fourier transform infrared spectroscopy (FTIR) and X‐ray photoelectron spectroscopy (XPS) confirmed the triethylamine grafting successfully on TiO2. Scanning electron microscope (SEM) results show that when the trimethylamine concentration is 1.0%, a uniform coating is formed on the surface of the carbon fiber. The interlaminar shear strength (ILSS) and interfacial shear strength (IFSS) were increased by 32% and 69%, respectively.

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Modification of Surface of Carbon Fiber Materials by Plasma Treatment (Review)

Cited by 8 publications

References 18 publications

A review of polymer surface modification by cold plasmas toward bulk functionalization

A review of polymer surface modification by cold plasmas toward bulk functionalization

Structure and Deformation Behavior of Polyphenylene Sulfide-Based Laminates Reinforced with Carbon Fiber Tapes Activated by Cold Atmospheric Plasma

Study on the enhancement of the interface performance between CF and polyimide by triethylamine grafting nano‐TiO₂ particles

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Modification of Surface of Carbon Fiber Materials by Plasma Treatment (Review)

Cited by 8 publications

References 18 publications

A review of polymer surface modification by cold plasmas toward bulk functionalization

A review of polymer surface modification by cold plasmas toward bulk functionalization

Structure and Deformation Behavior of Polyphenylene Sulfide-Based Laminates Reinforced with Carbon Fiber Tapes Activated by Cold Atmospheric Plasma

Study on the enhancement of the interface performance between CF and polyimide by triethylamine grafting nano‐TiO2 particles

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Study on the enhancement of the interface performance between CF and polyimide by triethylamine grafting nano‐TiO₂ particles