2004
DOI: 10.1007/978-1-4419-9048-8_22
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Modelling Transition Metal Nanoparticles: the Role of Size Reduction in Electronic Structure and Catalysis

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Cited by 2 publications
(2 citation statements)
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“…This effect could be attributed to the redistribution rather than to the narrowing of the 5d states [7][8][9][10][11]. The Au/FeO x /SiO 2 /Si(100) model system has gold in its zero valence state even during size reduction induced by Ar+ ion bombardment.…”
Section: Investigation On Model Au/fe 2 O 3 Systemmentioning
confidence: 99%
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“…This effect could be attributed to the redistribution rather than to the narrowing of the 5d states [7][8][9][10][11]. The Au/FeO x /SiO 2 /Si(100) model system has gold in its zero valence state even during size reduction induced by Ar+ ion bombardment.…”
Section: Investigation On Model Au/fe 2 O 3 Systemmentioning
confidence: 99%
“…While the morphology, electron structure and catalytic activity of the Au/FeO x /SiO 2 /Si(100) model (AuPLD), and the coprecipitated Au/Fe 2 O 3 (AuCP) samples in response to the oxygen and the subsequent hydrogen treatments are similar [15] it is reversed for the Au-Fe/HY (AuHY) sample. The difference cannot be ascribed to the change in particle size because the average diameter of gold particles is always in the range 4-6 nm, and is only slightly modified by oxygen/hydrogen treatments.…”
Section: Investigation On Model Au/fe 2 O 3 Systemmentioning
confidence: 99%