Modelling the Effect of Temperature on the Stability of Bromide and Carbonate Complexes of Europium, Gadolinium, Terbium and Determination of their Thermodynamic Functions
Abstract:A method has been developed for calculating the stability constants of inorganic complexes of rare-earth metals at various temperatures, based on analysis of the literature data by obtaining a linear regression equation on the form: . Using this method, the stability constants of bromide LnBr2+ and carbonate LnCO3+ complexes of europium, terbium, and gadolinium in aqueous solutions at temperatures of 50, 75, and 100 ° C were obtained. The obtained values of the coefficients А(T1) and В(T1) of the linear regres… Show more
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