Modelling of the kinetic of 2-chlorophenol catalytic photooxidation

Photocatalytic intrinsic reaction kinetics I: Mineralization of dichloroacetic acid

“…On the other hand for e a large enough, the square root dependence with respect to the LVRPA will be obtained. This type of behavior have been repeatedly reported (Wyness et al, 1994;Rideh et al, 1997Rideh et al, , 1999Herrmann, 1999;Okamoto et al, 1985;Bockelmann et al, 1991;Giménez et al, 1999).…”

Singlet molecular oxygen application for 2-chlorophenol removal

“…In the field of the environmental protection, this approach has been presented by many authors [8][9][10]. These works usually refer to the photocatalytic process with TiO 2 as a catalyst.…”

“…Actually, there are experimental constants describing the rate of degradation in definite experimental conditions and true for a definite range of substrate concentrations. However, some authors [8,9] try to relate more or less the experimental parameters to adsorption constants, and even to fix their relationships with elementary consequential reactions resulting from the reaction mechanism [12]. According to our knowledge, the photosensitized oxidation with an immobilized sensitizer has not been analyzed yet from the point of view of a kinetic description.…”

Photocatalytic Processes in Membrane Reactors

“…When the molecules or their by-products react together (chemical interaction), the proposed L-H kinetic equation is [136,179,180] r S1 ¼ k S1 S1 S2 ¼ k S1 K S1 C S1 K S2 C S2 ð1 þ K S1 C S1 þ K S2 C S2 Þ 2…”