Abstract. The atmospheric CO2 concentration increased by about 20 ppm
from 6000 BCE to the pre-industrial period (1850 CE). Several hypotheses have been
proposed to explain mechanisms of this CO2 growth based on either ocean
or land carbon sources. Here, we apply the Earth system model MPI-ESM-LR for
two transient simulations of climate and carbon cycle dynamics during this
period. In the first simulation, atmospheric CO2 is prescribed
following ice-core CO2 data. In response to the growing atmospheric
CO2 concentration, land carbon storage increases until 2000 BCE,
stagnates afterwards, and decreases from 1 CE, while the ocean continuously
takes CO2 out of the atmosphere after 4000 BCE. This leads to a missing
source of 166 Pg of carbon in the ocean–land–atmosphere system by the end of
the simulation. In the second experiment, we applied a CO2 nudging
technique using surface alkalinity forcing to follow the reconstructed
CO2 concentration while keeping the carbon cycle interactive. In that
case the ocean is a source of CO2 from 6000 to 2000 BCE due to a
decrease in the surface ocean alkalinity. In the prescribed CO2
simulation, surface alkalinity declines as well. However, it is not
sufficient to turn the ocean into a CO2 source. The carbonate ion
concentration in the deep Atlantic decreases in both the prescribed and the
interactive CO2 simulations, while the magnitude of the decrease in the
prescribed CO2 experiment is underestimated in comparison with
available proxies. As the land serves as a carbon sink until 2000 BCE due to
natural carbon cycle processes in both experiments, the missing source of
carbon for land and atmosphere can only be attributed to the ocean. Within
our model framework, an additional mechanism, such as surface alkalinity
decrease, for example due to unaccounted for carbonate accumulation processes on
shelves, is required for consistency with ice-core CO2 data.
Consequently, our simulations support the hypothesis that the ocean was a
source of CO2 until the late Holocene when anthropogenic CO2
sources started to affect atmospheric CO2.