The moisture sorption isotherm (MSI) is very useful for
biomass
drying and storage. In the present work, measured MSI data of herbaceous
and agricultural biomass (HAB) were collected from the literature.
The adsorption or desorption isotherms at the same temperatures (15,
20, 25, 30, 35, and 40 °C for adsorption and 20, 25, 30, and
35 °C for desorption) were compared, separately, to demonstrate
the similarity, evaluate the difference in the MSI among HABs, and
explore the feasibility of applying the similarity for MSI prediction.
It was observed that the MSIs of HABs at the same temperature are
similar, with most measurements falling within a range of ±20%
from an average given by a Guggenheim, Anderson, and de Boer (GAB)
model. The chemical composition and distinct sorption behaviors of
the biomass components were identified as the major factors determining
the similarity and defining the variation in the MSIs of HABs. Factors
associated with the measurement, including the temperature of drying
for sample preparation and uncertainty related to sample heterogeneity,
may cause the variation of the MSI comparable to the range of ±20%.
Considering the similarities among HABs, using the average to estimate
the MSI of an unknown HAB has a relative error of < ±20%.
Estimating the MSI based on the chemical composition and isotherms
of the major components (cellulose, lignin, and hemicelluloses as
well as the extractives) can achieve the same accuracy. Both may be
acceptable for practical applications. Additionally, it was found
from the comparison that HABs, on average, have evidently higher MSIs
than wood species mainly as a result of their higher contents of hemicellulose
and the extractives.