2019
DOI: 10.1016/j.polymer.2019.121681
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Modeling of the polymerization and crystallization kinetic coupling of polyamide 6 synthesized from ε-caprolactam

Abstract: HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des labor… Show more

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Cited by 10 publications
(28 citation statements)
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References 55 publications
(99 reference statements)
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“…The materials produced through T-RTM could be cheaper, safer and more recyclable, and in addition, they should be produced relatively fast due to their quick chemical reaction polymerization. So far, this quick reaction has been very difficult to control and model [11,12].…”
Section: Introductionmentioning
confidence: 99%
“…The materials produced through T-RTM could be cheaper, safer and more recyclable, and in addition, they should be produced relatively fast due to their quick chemical reaction polymerization. So far, this quick reaction has been very difficult to control and model [11,12].…”
Section: Introductionmentioning
confidence: 99%
“…1 shows that at 453 K the resin viscosity is directed by two growth regimes which are caused by the different time spans of the polymerization and the crystallization during the PA6 synthesis. Indeed, at 453 K the polymerization and the crystallization occur successively, which makes the lower slope between the two growth regimes the mark of the transition between these two phenomena [5]. Fig.…”
Section: Isothermal Rheology At 453 Kmentioning
confidence: 97%
“…The reactants used for PA6 polymerization in the rheological study comes from components provided by Brüggemann Chemical, Germany which are detailed in Table 1. The ratio of both the catalyst and the activator is defined at 0.79/1.10mol.% of the monomer, which was previously studied in order to determine its polymerization and crystallization kinetics [5]. To ensure minimal inhibition from humidity, the reactants are dried before use.…”
Section: Reactive MIXmentioning
confidence: 99%
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