Modeling and prediction of flame retardant performance of alkyl phosphinate using artificial neural network and adaptive neural fuzzy inference system

Abstract

The flame retardancy of polymer materials is closely linked to the types and compositions of flame retardants used. However, due to the complex relationships involved, it is difficult to quantify and predict flame retardancy using linear equations and models. Alkyl phosphinate flame retardants have emerged as promising candidates for their environmentally friendly, low toxicity, and excellent flame retardant properties. In this study, we aimed to develop a novel, low‐cost alkyl phosphinate flame retardant by predicting the quantitative impact of flame retardant composition on flame retardancy. To establish prediction models for the limiting oxygen index (LOI) value of alkyl phosphinate flame retardants, we utilized artificial neural network (ANN) and adaptive neural fuzzy inference system (ANFIS) programs, namely ANN, ANFIS‐grid partition (GP), and ANFIS‐subtractive clustering (SC). The prediction models were trained and validated, and their reliability was assessed based on the root mean square error (RMSE), coefficient of determination (R2), and mean absolute percentage error (MAPE) criteria. Our results indicate that the ANFIS‐SC prediction model exhibits the highest reliability, with high accuracy and ideal prediction results.