“…Highly ordered nanoparticle (NP) arrays can show optical response characterized by additional features compared to the case of individual NPs, for which the typical optical spectrum is mainly characterized by an absorption band, resulting from the excitation of the localized surface plasmon resonance (LSPR) [1]. In particular, the electromagnetic interaction between neighbouring NPs, mediated by near-or far-field coupling effects, can lead to the appearance of collective modes like Fano-resonances [2], grating-induced plasmon modes [3,4] and light waveguiding [5,6], which are of great interest since they could spread and strengthen the application of NP systems to photonic [7][8][9], sensing [10][11][12] or security technologies [13,14]. In recent years, though, much effort has been addressed to the exploration of different fabrication techniques to achieve precise control over the organization of metal NPs.…”