Microwave-absorbing catalyst H3PW12O40·xH2O/C (HPW/C)
was prepared for biodiesel
synthesis using cottonseed oil and methanol as feed materials. The
hot spot temperatures in the catalyst were calculated by considering
the absorbed microwave power, temperature rise, and heat transfer
between catalyst and liquid phase. The intrinsic kinetics model for
heterogeneous transesterification was established on the basis of
the Langmuir–Hinshelwood–Hougen–Watson (LHHW)
mechanism, and the model parameters were decided by using the kinetics
experimental data and the calculated results under the hot spot temperatures.
Results showed that the hot spot temperatures of the catalyst were
far higher than the temperature of bulk liquid, and the simulated
kinetics results agreed well with the experimental data.