“…Many crystals such as AgGaSiSe 4 , CuGaSnSe 4 , AgGeGaS 4 , and AgAlGeSe 4 have been studied [2][3][4]. Due to various reasons, some of them could not grow into single crystals, but the others, especially, AgGeGaS 4 (AGGS) crystal has been paid much attention because of its unique structure, special properties, including the capability of using as nonlinear optical element in second harmonic generation (SHG), difference frequency generation (DFG) and optical parametric amplification (OPA) [5][6][7][8]. Also, AGGS is the most promising material for parametric light generators in mid-far IR range with Nd:YAG laser radiation pumping due to the weak absorption around 1 mm, high radiative resistance (230 MW/cm 2 ), and large birefractive index [5].…”