Model analysis of zeolite-like phosphates and their adsorption complexes with water molecules

Silicophosphates containing SiO6octahedra – anhydrous synthesis under ambient conditions

“…5 This issue and related phenomena 12,13 like the transition of fourfold to five-and sixfold silicon species 12 have been studied. Although several theoretical investigations 14,15 have been carried out, the existence of SiO 6 octahedra and the role of phosphorus in this system are not completely understood.…”

Structural Insight into Layered Silicon Hydrogen Phosphates Containing [SiO6] Octahedra Prepared by Different Reaction Routes

“…[2] Not only in phosphorus containing glasses [3][4][5][6] but also in a number of crystalline silicophosphates, e.g. [18,19] Furthermore, the optical [20] and material properties [21] of silicophosphates, which are partly different from silicate materials due to the phosphorus content, are of basic interest relating to applications in laser technique, [22,23] implants research, [24] or [a] Additionally, molecular compounds with [SiO 6 ] moieties are also known in literature.…”

“…[17] The role of phosphorus for building up [SiO 6 ] octahedra in silicophosphates has been discussed in several theoretical investigations. [18,19] Furthermore, the optical [20] and material properties [21] of silicophosphates, which are partly different from silicate materials due to the phosphorus content, are of basic interest relating to applications in laser technique, [22,23] implants research, [24] or mental analysis (ICP-AES), and detailed NMR spectroscopic studies, including 1 H, 13 C, 29 Si, and 31 P MAS-, 31 P- 29 Si-REDOR, HETCOR, and CP-RFDR experiments. DFT calculations support the structure of Si(HPO 4 ) 2 consisting of layers of [SiO 6 ] octahedra linked by [O 3 P(OH)] tetrahedra.…”

“…Furthermore, a tris(imidodiphosphinato) silicon complex synthesized from bis(diphenyldiphosphinyl)imine and silicon(IV) chloride, offers [SiO 6 ] structures surrounded by phosphorus atoms . The role of phosphorus for building up [SiO 6 ] octahedra in silicophosphates has been discussed in several theoretical investigations , . Furthermore, the optical and material properties of silicophosphates, which are partly different from silicate materials due to the phosphorus content, are of basic interest relating to applications in laser technique,, implants research, or catalysis , .…”

“…[1] Typically, this phenomenon is only known from several high pressure materials and minerals, e.g. [18,19] Furthermore, the optical [20] and material properties [21] of silicophosphates, which are partly different from silicate materials due to the phosphorus content, are of basic interest relating to applications in laser technique, [22,23] implants research, [24] or [a] [2] Not only in phosphorus containing glasses [3][4][5][6] but also in a number of crystalline silicophosphates, e.g.…”