We have studied the use of tertiarybutylarsine (t-BuAsH2) for organometallic vapor phase epitaxy (OMVPE) growth of AlGaAs/GaAs heterojunction bipolar transistors (HBTs). Good dc characteristics were achieved with t-BuAsH2-grown HBT structures, including common-emitter current gains higher than 200 and 1000 for n-p-n and p-n-p structures, respectively. Near-ideal current gain dependence on the collector current density was observed, indicating that the quality of AlGaAs was suitable for high-performance HBTs. The microwave characteristics were also comparable to those of arsine-grown HBTs. These results demonstrate that t-BuAsH2 can successfully replace arsine for OMVPE growth of AlGaAs/GaAs HBT structures.