We study the S-wave DΞ bound state in the Bethe-Salpeter formalism in the ladder and instantaneous approximations. With the kernel generated by the hadronic effective Lagrangian, two open-charmed bound states, which quantum numbers are I = 0, J P = (1 2) − and I = 1, J P = (1 2) − , respectively, are predicted as new candidates of hadronic pentaquark molecules in our formalism. If existing, they could contribute to the broad 3188 MeV structure near the five new narrow Ω c states observed recently by the LHCb Collaboration.