Studies of the reaction γπ → ππ, in the context of the ongoing Primakoff program of the COM-PASS experiment at CERN, give access to the radiative couplings of the ρ(770) and ρ3(1690) resonances. We provide a vector-meson-dominance estimate of the respective radiative width of the ρ3, Γρ 3 →πγ = 48(18) keV, as well as its impact on the F -wave in γπ → ππ. For the ρ(770), we establish the formalism necessary to extract its radiative coupling directly from the residue of the resonance pole by analytic continuation of the γπ → ππ amplitude to the second Riemann sheet, without any reference to the vector-meson-dominance hypothesis.