Uncertainties in the thermonuclear rates of the 15 O(α, γ) 19 Ne and 18 F(p, α) 15 O reactions affect model predictions of light curves from type I X-ray bursts and the amount of the observable radioisotope 18 F produced in classical novae, respectively. To address these uncertainties, we have studied the nuclear structure of 19 Ne over Ex = 4.0 − 5.1 MeV and 6.1 − 7.3 MeV using the 19 F( 3 He,t) 19 Ne reaction. We find the J π values of the 4.14 and 4.20 MeV levels to be consistent with 9/2 − and 7/2 − respectively, in contrast to previous assumptions. We confirm the recently observed triplet of states around 6.4 MeV, and find evidence that the state at 6.29 MeV, just below the proton threshold, is either broad or a doublet. Our data also suggest that predicted but yet unobserved levels may exist near the 6.86 MeV state. Higher resolution experiments are urgently needed to further clarify the structure of 19 Ne around the proton threshold before a reliable 18 F(p, α) 15 O rate for nova models can be determined.