2002
DOI: 10.1103/physrevlett.88.113201
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X129eXeMolecular Spin Relaxation

Abstract: We identify the formation of bound 129Xe-Xe molecules as the primary fundamental spin-relaxation process at densities below 14 amagat. Low pressure Xe relaxation rate measurements as a function of gas composition show that Xe-Xe molecular relaxation contributes 1/T1 = 1/4.1 h to the total observed relaxation rate. The measured rate is consistent with theoretical estimates deduced from previously measured NMR chemical shifts. At atmospheric pressure the molecular relaxation is more than an order of magnitude st… Show more

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Cited by 56 publications
(55 citation statements)
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“…Typically, the optimum conditions in terms of long transverse relaxation times (T * 2 ) and high signal-to-noise ratio (SNR) were met at a gas mixture with pressures of 3 He : Xe (91% 129 Xe) : N 2 ≈ (2 : 8 : 35) mbar. Nitrogen was added to suppress spin-rotation coupling in bound Xe-Xe van der Waals molecules [18,19]. As unpolarized matter sample we used a cylindrical BGO crystal (Bi 4 Ge 3 O 12 , ρ=7.13 g/cm 3 ).…”
mentioning
confidence: 99%
“…Typically, the optimum conditions in terms of long transverse relaxation times (T * 2 ) and high signal-to-noise ratio (SNR) were met at a gas mixture with pressures of 3 He : Xe (91% 129 Xe) : N 2 ≈ (2 : 8 : 35) mbar. Nitrogen was added to suppress spin-rotation coupling in bound Xe-Xe van der Waals molecules [18,19]. As unpolarized matter sample we used a cylindrical BGO crystal (Bi 4 Ge 3 O 12 , ρ=7.13 g/cm 3 ).…”
mentioning
confidence: 99%
“…Typically, the optimum conditions in terms of long transverse relaxation times (T * 2 ) and high signal-to-noise ratio (SNR) were met at a gas mixture with pressures of ( 3 He, Xe (91% 129 Xe), N 2 )=(3, 5, 25) mbar. Nitrogen was added as buffer gas to suppress spin-rotation coupling in bound Xe-Xe van der Waals molecules [33,34]. In total 7 measurement runs (j = 1, .…”
mentioning
confidence: 99%
“…As discussed in detail in ref. [48], the T 1,Xe -time of 129 Xe in our pressure range is the combined effect of the density independent wall relaxation T 1,wall have to be optimized (Eq. (6)), the influence of the increased total gas pressure on the field gradient induced transverse relaxation time has to be reconsidered: In a gas mixture (GM) with N 2 as buffer gas, the resulting diffusion coefficients for 3 He and 129 Xe are given by [49] In Fig.9, the dependence of T 2 with vdW field…”
mentioning
confidence: 99%